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Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite

Authorized Users Only
2018
Authors
Kaluđerović, Lazar M.
Tomić, Zorica P.
Asanin, Darko P.
Durovic-Pejcev, Rada D.
Kresović, Branka
Article (Published version)
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Abstract
The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients sh...ow higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.

Keywords:
Montmorillonite / phenyltrimethylammonium chloride / batch equilibrium method / adsorption / infrared spectroscopy / X-ray diffraction
Source:
Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 2018, 53, 8, 503-509
Publisher:
  • Taylor & Francis Inc, Philadelphia
Funding / projects:
  • Minerals of Serbia: composition, genesis, application and contribution to the environmental sustainability (RS-176010)
  • Studies on plant pathogens, arthropods, weeds, and pesticides with a view to developing the methods of biorational plant protection and safe food production (RS-31043)

DOI: 10.1080/03601234.2018.1462930

ISSN: 0360-1234

PubMed: 29708850

WoS: 000443895800003

Scopus: 2-s2.0-85046100886
[ Google Scholar ]
1
1
URI
http://rik.mrizp.rs/handle/123456789/726
Collections
  • Радови истраживача / Researchers' publications
Institution/Community
MRIZP
TY  - JOUR
AU  - Kaluđerović, Lazar M.
AU  - Tomić, Zorica P.
AU  - Asanin, Darko P.
AU  - Durovic-Pejcev, Rada D.
AU  - Kresović, Branka
PY  - 2018
UR  - http://rik.mrizp.rs/handle/123456789/726
AB  - The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
T1  - Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite
VL  - 53
IS  - 8
SP  - 503
EP  - 509
DO  - 10.1080/03601234.2018.1462930
UR  - conv_986
ER  - 
@article{
author = "Kaluđerović, Lazar M. and Tomić, Zorica P. and Asanin, Darko P. and Durovic-Pejcev, Rada D. and Kresović, Branka",
year = "2018",
abstract = "The results presented in this paper show an impact of the concentration of the aromatic organic cation on the adsorption of acetochlor on the surface of the organic-modified montmorillonite. Natural montmorillonite from Bogovina (Boljevac municipality, Serbia) was used for organic modification in this experiment. Cation exchange capacity of this montmorillonite (86mmol 100g(-1) of clay) was determined using the methylene blue method. In pretreatment, montmorillonite was modified with NaCl. For the purpose of organic modification, three different concentrations of phenyltrimethylammonium chloride (PTMA) have been selected, based on calculated CEC value: 43mmol 100g(-1) of clay (0.5 CEC), 86mmol 100g(-1) of clay (1 CEC) and 129mmol 100g(-1) of clay (1.5 CEC). The changes in the properties of the inorganic and organic modified montmorillonite were examined using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and batch equilibrium method. Freundlich coefficients show higher uptake of the herbicide by montmorillonite modified with PTMA, compared to inorganic-modified montmorillonite. The results also indicate the influence of the organic cation concentration on the adsorption of the selected herbicide.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was",
title = "Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite",
volume = "53",
number = "8",
pages = "503-509",
doi = "10.1080/03601234.2018.1462930",
url = "conv_986"
}
Kaluđerović, L. M., Tomić, Z. P., Asanin, D. P., Durovic-Pejcev, R. D.,& Kresović, B.. (2018). Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was
Taylor & Francis Inc, Philadelphia., 53(8), 503-509.
https://doi.org/10.1080/03601234.2018.1462930
conv_986
Kaluđerović LM, Tomić ZP, Asanin DP, Durovic-Pejcev RD, Kresović B. Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite. in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was. 2018;53(8):503-509.
doi:10.1080/03601234.2018.1462930
conv_986 .
Kaluđerović, Lazar M., Tomić, Zorica P., Asanin, Darko P., Durovic-Pejcev, Rada D., Kresović, Branka, "Examination of the influence of phenyltrimethylammonium chloride (PTMA) concentration on acetochlor adsorption by modified montmorillonite" in Journal of Environmental Science and Health Part B-Pesticides Food Contaminants and Agricultural Was, 53, no. 8 (2018):503-509,
https://doi.org/10.1080/03601234.2018.1462930 .,
conv_986 .

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